Advanced functional organic and polymeric materials (4896) |
| Credits: 3,0 | | Study load hours: 81 | Period: semester 1 (3sp)  |
| Language of instruction: English |
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The student is familiar with the basic concepts of organic and polymer chemistry (as typically covered in a bachelor’s program in chemistry): nomenclature of organic compounds, conformational analysis, stereochemistry, aromaticity, resonance, tautomerism, basic concepts of reactivity (nucleophilic/electrophilic), typical organic reactions (substitutions, additions, eliminations), and the basics of radical polymerization
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Module 1: introduction to the course; introduction to organometallic chemistry; Heck, Suzuki, Stille, Sonogashira, Negishi, Ullmann and Buchwald-Hartwig reactions; introduction to conjugated polymers; PPVs and polythiophenes; push-pull type conjugated polymers (Suzuki, Stille, DArP); controlled synthesis of conjugated polymers
Module 2: controlled (radical and ionic) polymerizations; principles of photo-mediated polymerizations; photo-ATRP/RAFT; photo-cationic polymerizations; supramolecular interactions and their role in advanced materials; self-healing materials and dynamic interactions
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| Compulsory course material |
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For this course, PowerPoint slides and synthesis exercises are provided (via Blackboard). In addition, selected chapters from the textbooks listed below, review articles, and chapters from doctoral dissertations are used.
Textbooks:
Negishi, E., Handbook of Organopalladium Chemistry for Organic Synthesis; John Wiley & Sons: New York, NY, 2002, ISBN: 9780471315063
Hartwig, J. F., Organotransition Metal Chemistry: From Bonding to Catalysis; University Science Books, Sausalito, CA, 2009, ISBN: 9781891389535
Cieferri, A., Supramolecular Polymers; CRC Taylor & Francis, 2005, ISBN: 9780824723316
Moad, G.; Solomon, D. H., The Chemistry of Radical Polymerization, 2nd edition, Elsevier, 2005, ISBN: 9780080442884 |
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| Recommended reading |
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Title: Handbook of Organopalladium Chemistry for Organic Synthesis
Author: Negishi, E.
Edition: 1
Publisher: John Wiley & Sons: New York
ISBN: 9780471315063
Extra info: /
Title: Organotransition Metal Chemistry: From Bonding to Catalysis
Author: Hartwig, J. F.
Edition: 1
Publisher: University Science Books, Sausalito, CA
ISBN: 9781891389535
Extra info: /
Title: Supramolecular Polymers
Author: Cieferri, A.
Edition: 2
Publisher: CRC Taylor & Francis
ISBN: 9780824723316
Extra info: /
Title: The Chemistry of Radical Polymerization
Author: Moad, G.; Solomon, D. H.
Edition: 2
Publisher: Elsevier
ISBN: 9780080442884
Extra info: /
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| Mandatory software |
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For the Module 1 assignment, students will use SciFinder-n (a search engine available through the library's website) and the ChemBioOffice software package (licensed through MATCHEM). |
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Lecture ✔
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Response lecture ✔
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Exercises ✔
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Presentation ✔
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Semester 1 (3,00sp)
| Evaluation method | |
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| Oral evaluation during teaching period | 30 % |
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| Transfer of partial marks within the academic year | Yes, with condition |
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| Conditions transfer of partial marks within the academic year | The student obtains at least 10/20. |
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| Written exam | 70 % |
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| Transfer of partial marks within the academic year | Yes, with condition |
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| Conditions transfer of partial marks within the academic year | The student obtains at least 10/20. |
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| Evaluation conditions (participation and/or pass) | ✔ |
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| Conditions | Participation in the presentation, which is subject to evaluation, is mandatory. |
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| Consequences | In the event of an unjustified absence from the presentation to which the evaluation is linked, the student will receive an 'N' as the final grade for the entire course module: evaluation not fully completed due to unjustified absence from part(s) of the evaluation. |
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| Additional information | Regarding the improper use of genAI in this course, we refer to the guidelines of the study program and the lecturer on Blackboard.
For students with an exam contract, the presentation during the teaching period will be replaced by a presentation during the exam period. |
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Second examination period
| Evaluation second examination opportunity different from first examination opprt | |
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Learning outcomes | EC = learning outcomes DC = partial outcomes BC = evaluation criteria |
Master of Materiomics
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- EC
| EC 1. The graduate of the Master of Materiomics programme has an in-depth understanding of the fundamentals of functional materials, especially with regard to the relation between composition, structure and functional properties at all length scales and in their operating surroundings. | | | - DC
| DC1.1 The student is able to explain the structure of materials and apply this knowledge. | | | - DC
| DC1.2 The student is able to explain properties of materials and apply this knowledge. | | | - DC
| DC1.5 The student is able to explain synthesis and deposition methods for materials. | | | - DC
| DC1.6 The student can understand properties from the structure. | - EC
| EC 2. The graduate of the Master of Materiomics programme can combine chemical and physical principles enabling the discovery of new material concepts based on an interdisciplinary approach. | | | - DC
| DC2.1 The student is able to design a structure with properties in mind. | - EC
| EC 3. The graduate of the Master of Materiomics programme has insight in how modelling or synthesis methods predict and affect functional properties and is able to design sustainable materials based on in-operando functionality making optimal use of the synergy between computational and experimental methods. | | | - DC
| DC3.3 The student understands how a synthesis affects the properties of a material. | - EC
| EC 4. The graduate of the Master of Materiomics programme is able to autonomously consult, summarise and critically interpret international scientific literature, reference it correctly and use it to explore and identify new domains relevant to the field. | | | - DC
| DC4.3 The student is able to critically interpret, evaluate, compare, and/or summarize relevant scientific literature related to materials-related problems or research questions. | - EC
| EC 6. The graduate of the Master of Materiomics programme is able to communicate in both written and spoken form and to take a well-argued position in a scientific discussion, going from a general to a specialist level, adapted to the target audience. | | | - DC
| DC6.1 The student is able to report orally and in writing in an adequate manner. | | | - DC
| DC6.3 The student is able to take and defend a logically constructed position, based on relevant and scientifically supported arguments. |
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| Included in these programmes | Tolerance3 |
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Y
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2nd year Master of Materiomics traject opleidingsonderdelen
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Y
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1 Education, Examination and Legal Position Regulations art.12.2, section 2. |
| 2 Education, Examination and Legal Position Regulations art.15.1, section 3. |
3 Education, Examination and Legal Position Regulations art.16.9, section 2.
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